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This is the area in which the user is most likely to come into contact with solvents.
The thinner is usually composed of a solvent blend similar to that used in the product. Any attempts to use lower grade solvents in order to cheapen the thinner can have serious effects on the application, drying and appearance of the coating.
With 2 pack products, the thinner is usually part of the package.
With cellulose products, the so-called "economy" thinners (sold in bulk) contain poor quality solvents and large amounts of diluent to reduce the cost.
The effects are:
(i) Poor cutting power, i.e. more thinly needed to application viscosity, resulting in lower solids and build. This is for undercoats as well as topcoats.
(ii) Poor flow, due to lack of expensive high boilers.
(iii) Poor overspray absorption, due to lack of high boilers.
(iv) Low gloss, due to poor solvency for the binder.
(v) Blushing, due to poor solvency for the binder.
BLUSHING
The fault which can show as haze or milkiness or loss of gloss during the drying of lacquers.
Due to a faulty solvent balance, there are two ways in which it occurs.
(i) Resin Blush - Caused by precipitation of the NC or the modifying resin and due entirely to an unbalanced solvent mixture. It is important that the least volatile solvent (or highest boiler) continues to act as a solvent for both the NC and the resin during the drying process.
(ii) Water Blush - A more common fault is associated with the chilling of the lacquer. During evaporation of the solvents, the drop in temperature of the solvent cools the surrounding air, and if the humidity is sufficiently high, dew point may be reached, resulting in the deposition of water. The film of water penetrates the paint surface and causes incompatibility of the NC or resin, manifested by the haze of whitening described above.
The low boiling ketones (Acetone and MEX) tend to induce water blush. Medium and high boiling esters and alcohols impart good blush resistance.
THINNER COMPOSITION
1. CELLULOSE SPRAY THINNER
Component
% Composition
Boiling Point
Solvent Type
Toluene
30-35
111
Aromatic Hydrocarbon
Xylene
20-25
140
Aromatic Hydrocarbon
Acetone
10-15
56
Ketone
Methyl Ethyl Ketone
1 – 5
80
Ketone
Iso Propyl Alcohol
10-15
82
Alcohol
Iso Butyl Acetate
5 -10
108
Esters
Ethoxy Propanol
10-15
Alcohol
2. SYNTHETIC SPRAY THINNER
Component
% Composition
Boiling Point
Solvent Type
Xylene
55-60
140
Aromatic Hydrocarbon
White Spirit
15-20
155-195
Aliphatic Hydrocarbon
C9 Aromatic Hydrocarbons
5 -10
Aromatic Hydrocarbon
Petroleum (SPB6)
15-20
Aliphatic Hydrocarbon
3. 2 PACK SPRAY THINNER
Component
% Composition
Boiling Point
Solvent Type
Normal
Slow
n-Butyl Acetate
78-82
23-32
127
Esters
Methoxy Propyl Acetate
13-17
38-42
140-150
Esters
C9 Aromatic Hydrocarbons
3 – 7
28-32
Aromatic Hydrocarbons
4. FADE OUT THINNER
Component
% Composition
Boiling Point
Solvent Type
Xylene
8 -12
140
Aromatic Hydrocarbon
Acetone
58-62
56
Ketone
Methyl Ethyl Ketone
8 -12
80
Ketone
Methoxy Propyl Acetate
18-22
140-150
Ester
5. ONE PACK POLYURETHANE SPRAY THINNER
Component
% Composition
Boiling Point
Solvent Type
C9/C10 Aromatic Hydrocarbons
20-25
Aliphatic Hydrocarbon
Petroleum (SPB3)
75-80
98 – 122
Aliphatic Hydrocarbon
TERM USED IN MODULE 4.
Aliphatic Hydrocarbons
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Compounds containing simple carbon chains containing carbon and hydrogen only.
Aromatic Hydrocarbons
-
Derived from compounds producing 'sweet aroma now mainly benzine ring and related structures.
Saturated (Atoms per Carbon)
-
Maximum number of hydrogen.
Parafines
-
Referred to simple alkanes.
Isomers
-
Same chemical formula. Different structural formula.
C9 Aromatic Hydrocarbons
-
Nine carbon atoms present.
Functional Group
-
The chemical group present giving the characteristic properties to the material.
FUNCTIONAL GROUPS USED IN MODULE 4
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