• This is the area in which the user is most likely to come into contact with solvents.

    The thinner is usually composed of a solvent blend similar to that used in the product. Any attempts to use lower grade solvents in order to cheapen the thinner can have serious effects on the application, drying and appearance of the coating.

    With 2 pack products, the thinner is usually part of the package.

    With cellulose products, the so-called "economy" thinners (sold in bulk) contain poor quality solvents and large amounts of diluent to reduce the cost.

    The effects are:

    (i)                 Poor cutting power, i.e. more thinly needed to application viscosity, resulting in lower solids and build. This is for undercoats as well as topcoats.

    (ii)               Poor flow, due to lack of expensive high boilers.

    (iii)             Poor overspray absorption, due to lack of high boilers.

    (iv)             Low gloss, due to poor solvency for the binder.

    (v)               Blushing, due to poor solvency for the binder.

    BLUSHING

    The fault which can show as haze or milkiness or loss of gloss during the drying of lacquers.

    Due to a faulty solvent balance, there are two ways in which it occurs.

    (i)                 Resin Blush - Caused by precipitation of the NC or the modifying resin and due entirely to an unbalanced solvent mixture. It is important that the least volatile solvent (or highest boiler) continues to act as a solvent for both the NC and the resin during the drying process.

    (ii)               Water Blush - A more common fault is associated with the chilling of the lacquer. During evaporation of the solvents, the drop in temperature of the solvent cools the surrounding air, and if the humidity is sufficiently high, dew point may be reached, resulting in the deposition of water. The film of water penetrates the paint surface and causes incompatibility of the NC or resin, manifested by the haze of whitening described above.

    The low boiling ketones (Acetone and MEX) tend to induce water blush. Medium and high boiling esters and alcohols impart good blush resistance.

    THINNER COMPOSITION

    1.      CELLULOSE SPRAY THINNER

    Component

    % Composition

    Boiling Point

    Solvent Type

    Toluene

    30-35

    111

    Aromatic Hydrocarbon

    Xylene

    20-25

    140

    Aromatic Hydrocarbon

    Acetone

    10-15

    56

    Ketone

    Methyl Ethyl Ketone

    1 – 5

    80

    Ketone

    Iso Propyl Alcohol

    10-15

    82

    Alcohol

    Iso Butyl Acetate

    5 -10

    108

    Esters

    Ethoxy Propanol

    10-15

     

    Alcohol

    2.       SYNTHETIC SPRAY THINNER

    Component

    % Composition

    Boiling Point

    Solvent Type

    Xylene

    55-60

    140

    Aromatic Hydrocarbon

    White Spirit

    15-20

    155-195

    Aliphatic Hydrocarbon

    C9 Aromatic Hydrocarbons

    5 -10

     

    Aromatic Hydrocarbon

    Petroleum (SPB6)

    15-20

     

    Aliphatic Hydrocarbon

    3.      2 PACK SPRAY THINNER

    Component

    % Composition

    Boiling Point

    Solvent Type

     

    Normal

    Slow

     

     

    n-Butyl Acetate

    78-82

    23-32

    127

    Esters

    Methoxy Propyl Acetate

    13-17

    38-42

    140-150

    Esters

    C9 Aromatic Hydrocarbons

    3 – 7

    28-32

     

    Aromatic Hydrocarbons

     

    4.      FADE OUT THINNER

    Component

    % Composition

    Boiling Point

    Solvent Type

    Xylene

    8 -12

    140

    Aromatic Hydrocarbon

    Acetone

    58-62

    56

    Ketone

    Methyl Ethyl Ketone

    8 -12

    80

    Ketone

    Methoxy Propyl Acetate

    18-22

    140-150

    Ester

    5.      ONE PACK POLYURETHANE SPRAY THINNER

    Component

    % Composition

    Boiling Point

    Solvent Type

    C9/C10 Aromatic Hydrocarbons

    20-25

     

    Aliphatic Hydrocarbon

    Petroleum (SPB3)

    75-80

    98 – 122

    Aliphatic Hydrocarbon

     

    TERM USED IN MODULE 4.

    Aliphatic Hydrocarbons

    -           

    Compounds containing simple carbon chains containing carbon and hydrogen only.

    Aromatic Hydrocarbons

    -           

    Derived from compounds producing 'sweet aroma now mainly benzine ring and related structures.

    Saturated (Atoms per Carbon)

    -           

    Maximum number of hydrogen.

    Parafines

    -           

    Referred to simple alkanes.

    Isomers

    -           

    Same chemical formula. Different structural formula.

    C9 Aromatic Hydrocarbons

    -           

    Nine carbon atoms present.

    Functional Group

    -           

    The chemical group present giving the characteristic properties to the material.

    FUNCTIONAL GROUPS USED IN MODULE 4

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